Phosphates in martian meteorites are important carriers of trace elements, although, they are volumetrically minor minerals. PO4 also has potential as a biomarker for life on Mars. Here, we report measurements of the U-Th-Pb systematics of phosphates in the martian meteorite ALH 84001 using the Sensitive High Resolution Ion MicroProbe (SHRIMP) installed at Hiroshima University, Japan. Eleven analyses of whitlockites and 1 analysis of apatite resulted in a total Pb/U isochron age of 4018 +/- 81 Ma in the 238U/206Pb-207Pb/206Pb-204Pb/206Pb 3-D space, and a 232Th-208Pb age of 3971 +/- 860 Ma. These ages are consistent within a 95% confidence limit. This result is in agreement with the previously published Ar-Ar shock age of 4.0 +/- 0.1 Ga from maskelynite and other results of 3.8-4.3 Ga but are significantly different from the Sm-Nd age of 4.50 +/- 0.13 Ga based on the whole rock and pyroxene. Taking into account recent studies on textural and chemical evidence of phosphate, our result suggests that the shock metamorphic event defines the phosphate formation age of 4018 +/- 81 Ma, and that since then, ALH 84001 has not experienced a long duration thermal metamorphism, which would reset the U-Pb system in phosphates.

From November 1998 to January 1999, the 39th Japanese Antarctic Research Expedition (JARE) conducted a large-scale micrometeorite collection at 3 areas in the meteorite ice field around the Yamato Mountains, Antarctica. The Antarctic micrometeorites (AMMs) collected were ancient cosmic dust particles. This is in contrast with the Dome Fuji AMMs, which were collected previously from fresh snows in 1996 and 1997 and which represent modern micrometeorites. To determine the noble gas concentrations and isotopic compositions of individual AMMs, noble gas analyses were carried out using laser-gas extraction for 35 unmelted Yamato Mountains AMMs and 3 cosmic spherules. X-ray diffraction analyses were performed on 13 AMMs before the noble gas measurement and mineral compositions were determined. AMMs are classified into 4 main mineralogical groups, defined from the heating they suffered during atmospheric entry. Heating temperatures of AMMs, inferred from their mineral compositions, are correlated with 4He concentrations and reflect the effect of degassing during atmospheric entry. Jarosite, an aqueous alteration product, is detected for 4 AMMs, indicating the aqueous alteration during long-time storage in Antarctic ice. Jarosite-bearing AMMs have relatively low concentrations of 4He, which is suggestive of loss during the alteration. High 3He/4He ratios are detected for AMMs with high 20Ne/4He ratios, showing both cosmogenic 3He and preferential He loss. SEP (solar energetic particles)-He and Ne, rather than the solar wind (SW), were dominant in AMMs, presumably showing a preferential removal of the more shallowly implanted SW by atmospheric entry heating. The mean 20Ne/22Ne ratio is 11.27 +/- 0.35, which is close to the SEP value of 11.2. Cosmogenic 21Ne is not detected in any of the particles, which is probably due to the short cosmic ray exposure ages. Ar isotopic compositions are explained by 3-component mixing of air, Q, and SEP-Ar. Ar isotopic compositions can not be explained without significant contributions of Q-Ar. SEP-Ne contributed more than 99% of the total Ne. As for 36Ar and 38Ar, the abundance of the Q component is comparable to that of the SEP component. 84Kr and 132Xe are dominated by the primordial component, and solar-derived Xe is almost negligible.

We have done petrologic studies of brachinites Allan Hills (ALH) 84025, Elephant Moraine (EET) 99402, and EET 99407; bulk geochemical studies of EET 99402 and EET 99407; Ar- Ar studies of Brachina and EET 99402; and a Xe isotopic study of Brachina. Textural, mineral compositional, and bulk compositional evidence show that EET 99402 and EET 99407 are paired. ALH 84025, EET 99402, and EET 99407 have igneous textures. Petrofabric analyses of ALH 84025 and EET 99407 demonstrate the presence of lineations and probable foliations of olivine grains that support formation as igneous cumulates. Mineral minor element chemistry and bulk rock incompatible lithophile element contents of the brachinites are distinct from those of acapulcoite- lodranite clan meteorites, a suite of high-grade metamorphic rocks and anatectic residues. The differences demonstrate a higher blocking temperature of equilibration for the brachinites and that cumulus plagioclase is present in EET 99402, EET 99407, and probably ALH 84025, thus indicating an igneous origin. Brachinites are differentiated, ultramafic achondrites, and are not part of a suite of primitive achondrites. We infer that their parent asteroid is a differentiated body. Brachina has an excess of 129Xe correlated with reactor-produced 128Xe, demonstrating that short-lived 129I was present at the time of formation. This, plus literature data, attests to early formation of the brachinites, within a few Ma of the formation of chondrites. Ar-Ar age data show that Brachina and EET 99407 were degassed about 4.13 Ga ago, possibly by a common impact event. EET 99402 and EET 99407 show petrographic evidence for shock, including possible conversion of plagioclase to maskelynite followed by devitrification. Brachina is unshocked, making a direct association between the Ar-Ar age and textures ambiguous.

The first occurrence of stishovite in an iron meteorite, Muonionalusta (group IVA), is reported. The mineral occurs intimately mixed with amorphous silica, forming tabular grains up to ~3 mm wide, with a hexagonal outline. It was identified using X-ray diffraction and Raman microspectroscopy. The unit-cell parameters of stishovite are a = 4.165(3) Å and c = 2.661(6) Å, and its chemical composition is nearly pure SiO2. Raman spectra show relatively sharp bands at 231 and 754 cm-1 and a broad band with an asymmetric shape and a maximum around 500 cm-1. The rare grains are found within troilite nodules together with chromite, daubreelite, and schreibersite. From their composition and morphology, and by comparisons with silica inclusions in, e.g., the Gibeon IVA iron, we conclude that these rare grains represent pseudomorphs after tridymite. The presence of stishovite in Muonionalusta is suggested to reflect shock metamorphic conditions in the IVA parent asteroid during a cosmic impact event.

We surveyed the impact crater populations of Venus and the Moon, dry targets with and without an atmosphere, to characterize how the 3-dimensional shape of a crater and the appearance of the ejecta blanket varies with impact angle. An empirical estimate of the impact angle below which particular phenomena occur was inferred from the cumulative percentage of impact craters exhibiting different traits. The results of the surveys were mostly consistent with predictions from experimental work. Assuming a sin2-Phi dependence for the cumulative fraction of craters forming below angle Phi, on the Moon, the following transitions occur: <~45 degrees, the ejecta blanket becomes asymmetric; <~25 degrees, a forbidden zone develops in the uprange portion of the ejecta blanket, and the crater rim is depressed in that direction; <~15 degrees, the rim becomes saddle-shaped; <~10 degrees, the rim becomes elongated in the direction of impact and the ejecta forms a “ butterfly” pattern. On Venus, the atmosphere causes asymmetries in the ejecta blanket to occur at higher impact angles. The transitions on Venus are: <~55 degrees, the ejecta becomes heavily concentrated downrange; <~40 degrees, a notch in the ejecta that extends to the rim appears, and as impact angle decreases, the notch develops into a larger forbidden zone; <~10 degrees, a fly-wing pattern develops, where material is ejected in the crossrange direction but gets swept downrange. No relationship between location or shape of the central structure and impact angle was observed on either planet. No uprange steepening and no variation in internal slope or crater depth could be associated with impact angle on the Moon. For both planets, as the impact angle decreases from vertical, first the uprange and then the downrange rim decreases in elevation, while the remainder of the rim stays at a constant elevation. For craters on Venus <~15 km in diameter, a variety of crater shapes are observed because meteoroid fragment dispersal is a significant fraction of crater diameter. The longer path length for oblique impacts causes a correlation of clustered impact effects with oblique impact effects. One consequence of this correlation is a shallowing of the crater with decreasing impact angle for small craters.