Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by Xray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO-rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr-rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr-rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr3+. Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re-enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to subdivide types 3.0 and 3.1 into types 3.00 through 3.15. On this basis, the most primitive ordinary chondrite known is Semarkona, although even this meteorite has experienced a small amount of metamorphism. Allan Hills (ALH) A77307 is the least metamorphosed CO chondrite and shares many properties with the ungrouped carbonaceous chondrite Acfer 094. Analytical problems are significant for glasses in type II chondrules, as Na is easily lost during microprobe analysis. As a result, existing schemes for chondrule classification that are based on the alkali content of glasses need to be revised.

The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass-rich basalts with Martian meteorite-like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 degrees C) temperatures in air and CO2, respectively, form thin (<1 micrometer) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and nearinfrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite-like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.

We present the basic differential equations of meteor physics (the single body equations). We solve them numerically including two possible types of fragmentation: into large pieces and into a cluster of small fragments. We have written a Fortran code that computes the motion, ablation and light intensity of a meteoroid at chosen heights, and allows for the ablation and shape density coefficients sigma and K, as well as the luminous efficiency tau, to be variable with height/time. We calibrated our fragmentation model (FM) by the best fit to observational values for the motion, ablation, radiation, fragmentation and the terminal masses (recovered meteorites) for the Lost City bolide. The FM can also handle multiple and overlapping meteor flares. We separately define both the apparent and intrinsic values of sigma, K, and tau. We present in this paper values of the intrinsic luminous efficiency as function of velocity, mass, and normalized air density. Detailed results from the successful application of the FM to the Lost City, Innisfree, and Beneov bolides are also presented. Results of applying the FM to 15 bolides with very precise observational data are presented in a survey mode (Table 7). Standard deviations of applying our FM to all these events correspond to the precision of the observed values. Typical values of the intrinsic ablation coefficient are low, mostly in the range from 0.004 to 0.008 s2 km^(-2), and do not depend on the bolide type. The apparent ablation coefficients reflect the process of fragmentation. The bolide types indicate severity of the fragmentation process. The large differences of the "dynamic" and "photometric" mass from numerous earlier studies are completely explained by our FM. The fragmentation processes cannot be modeled simply by large values of the apparent ablation coefficient and of the apparent luminous efficiency. Moreover, our new FM can also well explain the radiation and full dynamics of very fast meteoroids at heights from 200 km to 130 km.

The impact-induced hydrothermal system in the well-preserved, 4 km-diameter Kärdla impact crater on Hiiumaa Island, western Estonia, was investigated by means of mineralogical, chemical, and stable degrees C and O isotope studies. The mineralization paragenetic sequence, with gradually decreasing temperature, reveals at least three evolutionary stages in the development of the post-impact hydrothermal system: 1) an early vapor-dominated stage (>300 degrees C) with precipitation of submicroscopic adularia type K-feldspar; 2) the main stage (300 to 150/100 degrees C) with the development of a two-phase (vapor to liquid) zone leading to precipitation of chlorite/corrensite, (idiomorphic) euhedral K-feldspar, and quartz; and 3) a late liquid-dominated stage (<100 degrees C) with calcite I, dolomite, quartz, calcite II, chalcopyrite/pyrite, Fe-oxyhydrate, and calcite III precipitation.