Melt particles found at various depths in impactites from the Yaxcopoil-1 borehole into the Chicxulub impact structure (Yucatán) have been analyzed for their major and trace element abundances. A total of 176 electron microprobe and 45 LA-ICP-MS analyses from eight different melt particles were investigated. The main purpose of this work was to constrain the compositions of precursor materials and secondary alteration characteristics of these melt particles. Individual melt particles are highly heterogeneous, which makes compositional categorization extremely difficult. Melt particles from the uppermost part of the impactite sequence are Ca- and Na-depleted and show negative Ce anomalies, which is likely a result of seawater interaction. Various compositional groupings of melt particles are determined with ternary and binary element ratio plots involving major and trace elements. This helps distinguish the degree of alteration versus primary heterogeneity of melt phases. Comparison of the trace element ratios Sc/Zr, Y/Zr, Ba/Zr, Ba/Rb, and Sr/Rb with compositions of known target rocks provides some constraints on protolith compositions; however, the melt compositions analyzed exceed the known compositional diversity of possible target rocks. Normalized REE patterns are unique for each melt particle, likely reflecting precursor mineral or rock compositions. The various discrimination techniques indicate that the highly variable compositions are the products of melting of individual minerals or of mixtures of several minerals. Small, angular shards that are particularly abundant in units 2 and 3 represent rapidly quenched melts, whereas larger particles (>0.5 mm) that contain microlites and have fluidal, schlieric textures cooled over a protracted period. Angular, shard-like particles with microlites in unit 5 likely crystallized below the glass transition temperature or underwent fragmentation during or after deposition.

Thirteen new meteorites and three meteorite inclusions have been analyzed. Their results have been incorporated into earlier published data for a comprehensive reference to all analyzed meteorites at the Smithsonian Institution. The six tables facilitate a convenient overlook of meteorite data. Table 1 presents an alphabetical list of analyzed meteorites, Table 2 chemical analyses of stony meteorites, Table 3 chemical analyses of iron meteorites, Table 4 elemental composition of stony meteorites, Table 5 average composition of carbonaceous chondrites and achondrites (falls and finds), and Table 6 presents average composition of H, L, LL, and Antarctic chondrites (falls and finds). The tables are available online at the journal's Web site http://meteoritics.org

The proposed Sirente crater field consists of a slightly oblong main structure (main crater) 120 m in width and about 30 smaller structures (satellite craters), all in unconsolidated but stiff carbonate mud. Here we focus on the subsurface structure of the satellite craters and compare the Sirente field with known meteorite crater fields. We present a more complete outline of the crater field than previously reported, information on the subsurface morphology of a satellite crater (C8) 8 m in width, radiocarbon and thermoluminescence (TL) ages of material from this crater, and evidence for heated material in both crater C8 and the rim of the main crater. Crater C8 has a funnel shape terminating downwards, and evidence for soil injection from the surface to a depth of 9 m. The infill contained dispersed charcoal and small, irregular, porous fragments of heated clay with a calibrated age of B.P. 1712 (13C-corrected radiocarbon age: B.P. 1800 +/- 100) and a TL age of B.P. 1825 (calculated error +/- 274). Together with previous radiocarbon age (B.P. 1538) of the formation of the main crater (i.e., target surface below rim), a formation is suggested at the beginning of the first millennium A.D. Although projectile vaporization is not expected in Sirente-sized craters in this type of target material, we used geochemistry in an attempt to detect a meteoritic component. The results gave no unequivocal evidence of meteoritic material. Nevertheless, the outline of the crater field, evidence of heated material within the craters, and subsurface structure are comparable with known meteorite crater fields.

In order to elucidate the formation of low-H kaersutites in Martian meteorites, the Fe3+/Sigma-Fe ratio of Chassigny kaersutites in magmatic inclusions was directly determined by the synchrotron microXANES analysis. XANES analysis for standard kaersutites with known Fe3+/Sigma-Fe ratios shows a linear relationship between centroid energy positions of XANES pre-edge spectra and the Fe3+/Sigma-Fe ratio. Based on the linear relationship, the Fe3+/Sigma-Fe ratio of Chassigny kaersutites is estimated to be about 0.05. The low Fe3+/Sigma-Fe ratio clearly suggests that low-H kaersutites in Chassigny are not likely to be formed by the oxidation-dehydrogenation reactions. The low-H content of the Chassigny kaersutites is mainly due to the presence of a Ti oxy-component.

The Martian meteorite Yamato (Y-) 980459 is an olivine-phyric shergottite. It has a very primitive character and may be a primary melt of the Martian mantle. We have conducted crystallization experiments on a synthetic Y-980459 composition at Martian upper mantle conditions in order to test the primary mantle melt hypothesis. Results of these experiments indicate that the cores of the olivine megacrysts in Y-980459 are in equilibrium with a melt of bulk rock composition, suggesting that these megacrysts are in fact phenocrysts that grew from a magma of the bulk rock composition. Multiple saturation of the melt with olivine and a low-calcium pyroxene occurs at approximately 12 +/- 0.5 kbar and 1540 +/- 10 degrees C, suggesting that the meteorite represents a primary melt that separated from its mantle source at a depth of ~100 km. Several lines of evidence suggest that the Y-980459 source underwent extensive melting prior to and/or during the magmatic event that produced the Y-980459 parent magma. When factored into convective models of the Martian interior, the high temperature indicated for the upper Martian mantle and possibly high melt fraction for the Y-980459 magmatic event suggests a significantly higher temperature at the core-mantle boundary than previously estimated.